What changes in real operation
The useful window depends on band, season, solar conditions, geography, and whether one or both ends of the path are near the terminator. It is an opportunity, not a guaranteed opening.
The shortcut that causes trouble
Treating a world-map terminator line as a promise ignores absorption, MUF, noise, and the actual path between the stations.
Put it into practice
Compare sunrise and sunset at both ends, watch current ionospheric conditions, try adjacent bands before the window, and log which paths and frequencies actually improve.
Use current equipment instructions, battery and controller limits, measurement references, operating rules, and observed propagation. Planning values and propagation labels are not guarantees.